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You can select the rubber stamp by pressing S or, if the pattern stamp tool is visible in the toolbox, by pressing S twice (or Shift+S, depending on your tool-switch setting in the Preferences dialog box). To clone part of an image, Alt-click in the image window to specify a point of reference in the portion of the image you want to clone. Then click or drag with the tool in some other region of the image to paint a cloned spot or line. In Figure 7-2, for example, I Alt-clicked above and to the right of the bird s head, as demonstrated by the appearance of the stamp pickup cursor. I then painted the line shown inside the white rectangle. The rubber stamp cursor shows the end of my drag; the clone reference crosshair shows the corresponding point in the original image. The rubber stamp clones the image as it existed before you began using the tool. Even when you drag over an area containing a clone, the tool references the original appearance of the image. This prevents you from creating more than one clone during a single drag and produces the entirely predictable effect pictured in Figure 7-3.

These questions deal with data integrity They help you de ne some of the integrity constraints that you will build into the database What values are allowed in which elds Which elds are required (For example, does a customer record need a phone number A fax number An email address One of those but not all of them ) What are the valid domains (allowed values) for various elds What phone number formats are allowed How long can customer names be Addresses Do addresses need extra lines for suite or apartment number Do addresses need to handle US.

. . . . .

ZIP Codes such as 12345 ZIP+4 Codes such as 12345-6789 Canadian postal codes such as T1A 6G9 Or other countries postal codes Which elds should refer to foreign keys (For example, an address s State eld might need to be in the States table and a CustomerID eld might need to be in the Customers table I ve seen customers with a big list of standard comments and a Comments eld can only take those values) Should the system validate cities against postal codes (For example, should it verify that the 10005 ZIP Code is in New York City, New York That s cool but a bit tricky and can involve a lot of data.

35 8

) Do you need a customer record before you can place orders If a customer cancels an account, do you want to delete the corresponding records or just ag them as inactive What level of system reliability is needed Does the system need 24/7 access How volatile is the data How often does it need to be backed up How disastrous will it be if the system crashes How quickly do you need to be back up and running How painful will it be if you lose some data during a crash.

Once your system gets up and running, you can check important hardware settings before you install Windows XP Media Center Edition 2005 on that hardware, if you like As you boot your machine, you can instruct the motherboard to let you inspect existing CMOS settings during that process (for most motherboards, this requires pressing the Delete (del) key before POST runs to completion) At this point, what you need to check is pretty limited You ll normally worry about only a small number of settings at this point You want to make sure the CPU is running at the desired speed (which may not be its rated speed, for those who choose to underclock hotter, faster CPUs).

by the excited matrix molecules, presumably by a process of proton transfer similar to CI. A molecular ion (M + H) is generated by this transfer. Although singly-charged ions predominate in MALDI spectra, ions which are multi-charged are also formed. Because of the fact that laser radiation is used discontinuously as a pulse, this ionization mode lends itself to use of TOF analyzers. It is possible therefore to use this technique to analyse large macromolecules such as proteins, glycoproteins, oligonucleotides and oligosaccharides. The technique is especially versatile allowing MS analysis without signi cant sample fragmentation. A disadvantage is the dif culty of observing low molecular mass ions (e.g. <1000 Da) due to the presence of ions due to the

Equation (3.43) resembles the formula [equation (3.44)] adopted by Wolfsberg and Helmholtz [59] for the interaction matrix elements. This form, with the empirical factor k 1X75, was adopted by Ho mann in his derivation of extended Huckel theory [60], namely hAB k hAA hBB SAB 2 k 1X75 recall hAA e eA and hBB e eB 3X44